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Straightforward Pre-intermediate Pdf

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The way forward. Goodbye! My dossier. Answers. Contents. Welcome to your Straightforward. Pre-intermediate Portfolio. Unit 1 | Main vocabulary. Straightforward | Pre-Intermediate. Word. Frequency of Use. Part of Speech Phonetic Spelling. Definition. Sample Sentence clothes. ***. The Straightforward series is well loved for its pick-up-and-use practicality Straightforward's strong reading syllabus. Philip Kerr - Pre-intermediate, Unit 8.

Our research group have reported a different form of switchable cataysis where orthogonal metal-chain end-group reactivity enables high monomer selectivity and provides a route to switch between different polymerizations 17 , 18 , 19 , 21 , 23 , Other researchers have successfully applied the same switchable polymerization method to di-zinc 20 , di-aluminium 29 and transition metal 30 catalysts.

A requirement for successful catalysis is that the ROCOP cycles yield highly alternating polyesters, i. One consequence is that none of the previously reported systems show any appreciable epoxide homopolymerization and thus blocks featuring polyether linkages are inaccessible.

Here, we overcome this deficiency and describe catalytic processes delivering block and multiblock polymers featuring ether and ester linkages from monomer mixtures.

In these prior ROCOP studies the formation of ether linkages or blocks was not observed but the reactions were conducted with equivalent epoxide:anhydride loadings which would prevent observation of epoxide ROP following the alternating enchainment. Additionally, related bimetallic Cr-salen complexes were effective stereoselective propene oxide ROP catalysts, suggesting that under proper conditions the catalysts might be able to enchain polyether blocks 34 , This lack of cyclohexene oxide ROP, even when the epoxide was applied in excess, is proposed to be due to the higher relative barrier to cyclohexene ROP compared to propene oxide The polymerization was conducted using a small excess of alcohol vs.

Adding alcohols to these polymerizations causes fast and reversible equilibration with the propagating metal alkoxide intermediate resulting in controlled polymerization 38 , 39 , Initially, 1,2-trans-cyclohexane diol CHD was selected to allow for chain-growth simultaneously on both sides of the CTA, thereby yielding symmetric polyols. To investigate whether both monomers were incorporated randomly or if well-defined block-sequences were obtained, the reaction was monitored by both regular aliquot removal and analysis by 1H NMR spectroscopy and GPC Fig.

The polymerization kinetic profiles were analysed by applying fits to the conversion vs. To examine the polymer structure, the reaction aliquots were analysed by GPC as the reaction progressed Fig.

Plotting the molar mass data vs. The fits are in line with the kinetic data obtained from NMR spectroscopy.

The molar mass data and fits suggest the product is a block polymer rather than a polymer mixture because the latter outcome should result in at least two molar mass distributions.

The difference between the switchable catalyst and these control experiments provides good support for the formation of block polymers. The polymerization was also allowed to maintain contact with the catalyst system for 12 h after reaction completion and the molar mass distribution did not broaden.

These findings are consistent with minimal transesterification side-reactions occurring under these conditions Fig. The reaction product showed a single diffusion coefficient but a blend of the analogous polyester and polyether of similar molar masses to the constituent blocks showed two different diffusion rates.

Overall the formation of a block polymer is indicated by all the analytical techniques and spectroscopies and it is an ABA type poly ether-b-ester-b-ether. The selectivity is consistent with other metal-based catalysts for propene oxide ring-opening polymerizations 2.

The relative stereochemistry of the ester-linkages PE is a mixture of cis:trans linkages, as determined by reductive degradation experiments using lithium aluminium hydride, and indicating some linkage epimerisation during polymerization Supplementary Fig.

The two catalytic cycles connect through a chromium alkoxide intermediate which forms after propene oxide ring-opening. During the first phase of the polymerization, TCA1-PO ROCOP occurs and the kinetic data indicate that anhydride ring-opening is fast pre-rate limiting resulting in the catalyst resting state being the chromium carboxylate intermediate.

This intermediate subsequently reacts with propene oxide to re generate a chromium alkoxide which rapidly inserts the anhydride Fig. The high monomer selectivity is proposed to result because of both the Cr-carboxylate thermodynamic stability and the faster rates of anhydride compared to epoxide insertion into the Cr-alkoxide.

The precise speciation, nuclearity and coordination environments of these Cr III catalytic intermediates are not yet known and, indeed, the metal salen catalyst coordination chemistry remains a hot-topic 42 , 43 , 44 , All the polyols are amorphous and show a single glass-transition temperature, which can be tuned by the epoxide choice.

Unsaturated groups were observed to undergo cross-linking resulting in gelling during isolation of the polymers. The anhydride scope experiments allow two further guidelines: iii Anhydrides showing minimal steric hindrance result in broadened molar mass distributions, perhaps due to transesterification side-reactions; and iv Well-defined block polymers result when using sterically encumbered bi- and tricyclic anhydrides Primary and secondary alcohols resulted in good control and yielded polymers showing narrow, monomodal molar mass distributions.

Easy access to oxygenated block polymers via switchable catalysis

Comparing mono-, bi-, tri- and hexafunctional alcohols reveals that as steric bulk increases the chain-transfer reactions slow and more complex product distributions result. All the catalysis recommendations are summarised in Fig. From 1 to 4 mixture additions allowed isolation of multi-block polymers comprising 3, 7, 11 and 15 blocks, respectively.

It was proposed that another catalytic cycle might be accessible during these switch polymerizations provided there were no significant cross-over between ROP of PO and DL.

The catalysis using three-component mixtures was also highly selective and only a minimal tapered region featuring PPO and PDL was obtained, as indicated by the 1H NMR spectra for the final pentablock polymer Supplementary Figs. See Supplementary Fig.

The focus of this work is necessarily to establish the guidelines, scope and proof for the catalysis. You should see the rendered example above update accordingly.

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Here we are encountering something new. The v-bind attribute you are seeing is called a directive. Directives are prefixed with v- to indicate that they are special attributes provided by Vue, and as you may have guessed, they apply special reactive behavior to the rendered DOM.

You should see the message disappear. This example demonstrates that we can bind data to not only text and attributes, but also the structure of the DOM. There are quite a few other directives, each with its own special functionality.

You should see a new item appended to the list. If we think about it, almost any type of application interface can be abstracted into a tree of components: In Vue, a component is essentially a Vue instance with pre-defined options.

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We should be able to pass data from the parent scope into child components. We also need to provide each component with a "key", which will be explained later. In a large application, it is necessary to divide the whole app into components to make development manageable. However, there are a few key differences: The Web Components Spec has been finalized, but is not natively implemented in every browser. Safari We also need to provide each component with a "key", which will be explained later.

I had generally liked the direction of things until the hip hop yoga. Here we are encountering something new. Vue components provide important features that are not available in plain custom elements, most notably cross-component data flow, custom event communication and build tool integrations. Other researchers have successfully applied the same switchable polymerization method to di-zinc 20 , di-aluminium 29 and transition metal 30 catalysts.

And I do like that more and more practices keep getting added.